QTAIM and ELF topological analyses of zinc-amido complexes

The structures of three dinuclear zinc-amido complexes, involved in the very first step preparation zinc oxide nanoparticles via an organometallic route, have been investigated by density functional theory computational studies. various zinc–nitrogen and zinc–cyclohexyl bonds are finely characterized using quantum atoms molecules electron localization function (ELF) topological analyses. results compared to analyses parent or zinc-alkyl for which experimental structure has already reported. original two-component dative bond is unravelled ELF analysis. Fukui indices condensed on basins allow comparison chemical reactivity complexes. larger sensitivity electrophilic attack terminal with respect bridging intracyclic evidenced.